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Heterometallic complexes containing both lanthanide and transition metals are of interest because they might serve as bimetallic catalysts or as precursors to bimetallic particles on oxide surfaces. Direct lanthanide-transition metal bonds are ideal for such purposes. However, bonds between transition metals and electropositive elements such as lanthanides are relatively rare. Few such compounds have been structurally characterized. Complexes with bridging ligands should be more accessible. Accordingly, investigations have mainly been limited to those containing the cyanide anion as a bridging ligand between lanthanide cations and the transition metals. The bidentate character of two of the four cyanides in [M(CN)4] has shown various types of structures in the solid state which are molecular, one-dimensional, or twodimensional. In this study, we have investigated synthesizing ion-paired lanthanide-transition heterobimetallic complex using bridging cyanide ligand. Described here is recent work that led to the preparation and characterization of a novel one dimensional array a Tm(III) complex of the type {(DMF)10Tm2[Pd(CN)4]3}8 prepared quantitatively from the reaction of TmCl3 and K2Pd(CN)4 (2 : 3 molar ratio). Here Tm(III) ions are bridged by the bidentate Pd(CN)4 anions.

bulletin of the korean chemical society

Synthesis and One Dimensional Structure of Novel Cyanide-Bridged Thulium-Palladium Heterobimetallic Complex {(DMF)10Tm2[Pd(CN)4]3}∞