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and activation parameters are also consistent with theproposed mechanism.Key Words : Nucleophilic substitution reaction, Pyridinolysis, Cross-interaction constant, Zwitterionic tetra-hedral intermediate, Stepwise mechanismIntroductionThe mechanisms of the aminolysis of aryl esters andcarbonates have been well established.

Kinetic Studies on the Structure-Reactivity of Aryl Dithiomethylacetates