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By applying a catalytic amount of indium trichloride, regioselective ring-opening of epoxides to β-hydroxy ethers was established. While the alcoholysis of styrene oxides produced S N 1-type product, the alcoholysis of a-heteroatom-substituted epoxides predominantly produced S N 2-type product.

InCl3-Catalyzed Regioselective Ring-Opening Reactions of Epoxides to β-Hydroxy Ethers

InCl₃-Catalyzed Regioselective Ring-Opening Reactions of Epoxides to β-Hydroxy Ethers