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(tpen =N,N,N',N'-tetrakis(2-pyridylmethyl)-1,2-ethanediamine) has beenidentified by X-ray crystallography. The copper(II) ion is surrounded by two amine N atoms and three pyridineN atoms of the ligand, making a distorted trigonal-bipyramid. Among the six potential N donor atoms (twoamine N and four pyridine N atoms), only one pyridine N atom remains uncoordinated. We examined structuralchanges on addition of Cl

Crystal Structures and Characterization of Copper(II) Complexes of N,N,N'N'-Tetrakis(2-pyridylmethyl)-1,2-ethanediamine