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found a change of the rate dertermining step in acidic regions. These results are very unique even though the feature of hydrolysis reactivity of N-acylimidazole deriva- tives depends on the structure of N-acylimidazole. But, when one changes the acyl group with the heteroaryl group to the benzoyl group having same leaving group, the pH rate profile for the hydrolysis reaction of N-benzoyl-2-phenyl- imidazole observed to be related with the diprotonated species of the substrate in acidic region. 3 If N-heteroarylimidazole having the strong electron withdrawing group in the leaving group is hydrolyzed, how does the feature of the hydrolysis reaction appear? This is our concerns in this study. And so, we have performed the

Kinetics Studies on the Hydrolysis Reactions of N-Heteroaryl-4(5)-nitroimidazoles