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The potentiometric response of electrode no. 4 based on 1,3-bisbridged cofacial-calix[6]crown-5-ether (IV) gave a sub-Nernstian (45.0 mV/decade) response and the best detection limit (-log a e p = 4.73) towards epinephrine. The responses are decreasing in the order of epinephrine > K + , dopamine > NH 4 + > norepinephrine > Na + . It is remarkable that the proposed electrode shows the reasonable selectivity to epinephrine against other catecholamine neurotransmitters (dopamine and norepinephrine) as well as alkali metal ions.

Epinephrine-Selective Electrode Based on Lipophilic 1,3-Bisbridged Cofacial-calix[6]crown-5-ether