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and suggested them asmodel compounds for the type I copper(II) site of bluecopper proteins since their physicochemical propertiesmimic interesting spectral and redox behaviors in the bluecopper centers. In the former compound, the copper atomadopted a distorted tetrahedral geometry with a dihedralangle of 68.07

Synthesis and Characterization of Pseudotetrahedral Copper(II) Dihalide Complexes with (s)-(-)-Nicotine