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In designing extended porous coordinationpolymers, the selection of appropriate ligands is crucial todetermining the structural outcome of target polymers. Inthis context, the concept of “node-spacer”, in which the nodecorresponds to a metal (or a metal complex) and the spacerto a linking ligand, has become a fundamental tool in therational design of crystalline architectures.

bulletin of the korean chemical society

Two-dimensional Copper Coordination Polymers Based on Paddle-Wheel Type Secondary Building Units of Cu2(CO2R)4: [Cu(1,3-BDC)(H2O)]·2H2O and [Cu2(OBC)2(H2O)2]·H2O (1,3-BDC = 1,3-benzenedicarboxylate; OBC = 4,4'-oxybis(benzoate))