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This study was investigated occurrence and distribution patterns of organophosphorus flame retardants (OPFRs) in Nakdong River basin (mainstream, tributaries and sewage treatment plant (STP) effluents). 3 (TCEP, TCPP and TBEP) out of 9 OPFRs were detected in 6 out of 20 sampling sites (mainstream and tributaries), The TCPP and TBEP concentration levels in mainstream samples were ND~114.9 ng/L ng/L and ND~49.1 ng/L, respectively. And the TCEP, TCPP and TBEP concentration levels in tributary samples were ND~1,865.3 ng/L, ND~519.2 ng/L and ND~210.4 ng/L, respectively. 4 (TBP, TCEP, TCPP and TBEP) out of 9 OPFRs were detected in effluents of 11 STPs around the Nakdong River basin. The TBP, TCEP, TCPP and TBEP concentration levels in 11 STP effluents were ND~458.5 ng/L, ND~2,932.7 ng/L, ND~1,320.7 ng/L and ND~655.2 ng/L, respectively. According to the sampling season, change ranges of distribution patterns and detected concentrations of OPFRs were highly variable in the same sampling sites.

Occurrence of Organophosphorus Flame Retardants (OPFRs) in Nakdong River Basin : Mainstreams, Tributaries and STP Effluents