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Purpose: Poly (3-hydroxybutyrate-hydroxyvalerate) displayed high dipole-dipole interaction, a high hydrogen bonding but low polar interaction, and was therefore expected to be miscible with solvents/plasticizers that exhibit similar pattern of cohesive interaction. To determine the applicability, or otherwise of the theory of the three dimensional solubility parameters to the formulation of poly (3hydroxybutyrate-hydroxyvalerate) polymeric coating system, and hence identify any limitation in the application of the theory. This aspect was investigated in the study. Method: The structural group contribution method was employed to compute the partial and total solubility parameters of the compounds – the biopol polymer, a series of organic solvents and plasticizers. The computed partial solubility parameters included: dipole-dipole (δd), polar (δp) and hydrogen bonding (δh). Following a standard procedure in the literatures, the δd and δp values were

tropical journal of pharmaceutical research

Limitation observed in the application of the three dimensional solubility parameters to the coating formulation of poly (3-hydroxybutyrate-hydroxyvalerate) systems