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Thermal stabilities of Pt(II) complexes: K[PtCl 3 (CH 2 =CHSiMe 3 )], K[PtCl 3 (CH 2 =CHCH 2 SiMe 3 )], K[(acac)PtCl(CH 2 =CHSiMe 3 )] and [PtCl(CH 2 =CHCH 2 SiMe 3 )] 2 , were examined. All complexes were found to be stable at room temperature but they decomposed without melting above about 90 o C. The allylsilane complex decomposed above about 125 o C. All complexes liberated chlorotrimethylsilane on decomposition, showing the facile cleavage of the C-Si bond by nucleophilic attack on the silicon by the chloride ion. ( E ),( E )-1,4-diphenyl-1,3-butadiene was stereoselectively synthesised in good yield from ( E )-β-styrylsilane in the presence of Zeise’s salt. KEY WORDS: Thermal analysis, Vinyl- and allylsilane platinum(II) π-complexes, Platinum(II) catalysed synthesis, ( E ),( E )-1,4-diphenyl-1,3-butadiene Bull. Chem. Soc. Ethiop. 2008 , 22(3), 445-448.

bulletin of the chemical society of ethiopia

&lt;b&gt;Thermal decomposition of vinyl- and allylsilane platinum(II) complexes and platinum(II)catalysed synthesis of (&lt;i&gt;E&lt;/i&gt;),(&lt;i&gt;E&lt;/i&gt;)-1,4-diphenyl-1,3-butadiene&lt;/b&gt;