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In this paper, we characterize Riemannian 4-manifold in terms of its almost Hermitian twistor spaces $(Z,g_t,\mathbb{J}_{\pm})$. Some special metric conditions (including Balanced metric condition, first Gauduchon metric condition) on $(Z,g_t,\mathbb{J}_{\pm})$ are studied. For the first Chern form of a natural unitary connection on the vertical tangent bundle over the twistor space $Z$, we can recover J. Fine and D. Panov's result on the condition of the first Chern form being symplectic and P. Gauduchon's result on the condition of the first Chern form being a (1,1)-form respectively, by using the method of moving frames.

Twistor geometry of Riemannian 4-manifolds by moving frames