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The photoluminescence properties of Eu2+-activated α’-Sr2SiO4 and α’-Ba2SiO4 with a high Eu2+ concentration were investigated. In the case of Sr2-xEuxSiO4, emission was shifted from 585 to 611 nm with increasing the total Eu2+ concentration (x) from 0.1 to 0.8. This trend was similar to that in Ba2-xEuxSiO4, where the emission was shifted from 513 to 545 nm. The large redshifts in both the excitation and emission spectra were discussed in terms of the Eu2+ occupancies on two kinds of M sites and their local structural changes (M: Sr and Ba).

optics and photonics journal

Large Redshifts in Emission and Excitation from Eu&amp;lt;sup&amp;gt;2+&amp;lt;/sup&amp;gt;-Activated Sr&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;SiO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; and Ba&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;SiO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; Phosphors Induced by Controlling Eu&amp;lt;sup&amp;gt;2+&amp;lt;/sup&amp;gt; Occupancy on the Basis on Crystal-Site Engineering