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The CO-ethene copolymerization has been efficiently carried out in the water/CH2Cl2 emulsion by using water insolvablePd(II) complexes. By using the surfactant SDS very high molecular weight copolymers have been obtained withhigh productivity (ca. 13,000 g/(gPd.h))

The Catalytic Copolymerization of Ethene with Carbon Monoxide Efficiently Carried out in Water-Dichloromethane-Sodium Dodecylsulfate Emulsion