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The crystallization in the three-component systems Rb2SO4-MSO4-H2O (M = Mg, Co, Ni, Cu, Zn) is studied by the method of isothermal decrease of supersaturation. It has been established that isostructural double compounds,    Rb2M(SO4)2·6H2O (M = Mg, Co, Ni, Cu, Zn), , crystallize from the ternary solutions within wide    concentration ranges. The infrared spectra are discussed with respect to the normal vibrations of the sulfate ions and water molecules. The unit-cell group theoretical treatment of the double salts is presented. The extent of energetic distortions of guest ions (about 2 mol%) matrix-isolated in the respective selenates, (M' = K, Rb, ; M" = Mg, Co, Ni, Cu, Zn), is commented.

journal of crystallization process and technology

Crystallization in the Three-Component Systems Rb&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;SO&amp;lt;sub&amp;gt;4-&amp;lt;/sub&amp;gt;MSO&amp;lt;sub&amp;gt;4-&amp;lt;/sub&amp;gt;H&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;O (M = Mg, Co, Ni, Cu, Zn) at 298 K