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The associative properties of methoxy (CH3O-) ended E58B11 and hydroxyl (-OH) ended E56B19 oxyethylene-oxybuty- lene diblock copolymers in aqueous solution at different temperature are reported in this paper. For both copolymers, E represents an oxyethylene (-[CH2CH2O]-) unit and B an oxybutylene (-[CH(C2H5)CH2O]-) unit while the subscripts denote the number average block length. Surface tension measurements were used to find out surface excess concentrations (Γm), area per molecule (αs1 ) at air/water interface and Gibbs free energy for adsorption (△G0ads ) for the pre-micellar region at four temperatures. Likewise thermodynamic parameters of micellization such as, critical micelle concentrations (CMC), enthalpy of micellization (△H0mic ), standard free energy of micellization (△G0mic) and entropy of micellization (△S0mic ), were also obtained using surface tension measurements. Solution densities were used to deter-mine the partial specific volume of micelle ( Vmic) and micellar density (ρmic). Dilute solution viscosities have been used to estimate the intrinsic viscosities [η], solute-solvent interaction parameter (KH) and hydration value of micelle (Wh) at various temperatures. The effect of temperature on the micelle properties is also discussed

international journal of organic chemistry

Surface Tension, Density and Viscosity Studies on the Associative Behaviour of Oxyethylene-Oxybutylene Diblock Copolymers in Water at Different Temperatures