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An efficient and versatile practical protocol for the chemoselective N-tert-butoxycarbonylation of amines using Nano-γ-Fe2O3 and (BOC)2O. Nano-γ-Fe2O3 was applied as an efficient, green, heterogeneous and reusable catalyst at ambient temperature; the method is general for the preparation of N-Boc derivatives of aliphatic, heterocyclic, aromatic as well as amino acid derivatives.

green and sustainable chemistry

Nano-γ-Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;: Efficient, Reusable and Green Catalyst for &lt;i&gt;N&lt;/i&gt;-&lt;i&gt;tert&lt;/i&gt;-Butoxycarbonylation of Amines in Water