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International audienceLiFePO4 materials synthesized using FePO4(H2O)2 and Li2CO3 blend were optimized in view of their use as positive electrodes in Li-ion batteries for hybrid electric vehicles. A strict control of the structural properties was made by the combination of X-ray diffraction, FT-infrared spectroscopy and magnetometry. The impact of the ferromagnetic clus-ters (γ-Fe2O3 or Fe2P) on the electrochemical response was examined. The electrochemical performances of the opti-mized LiFePO4 powders investigated at 60°C are excellent in terms of capacity retention (153 mAh*g-1 at 2C) as well as in terms of cycling life. No iron dissolution was observed after 200 charge-discharge cycles at 60°C for cells containing Li foil, Li4Ti5O12, or graphite as negative electrodes

Enhanced Electrochemical Properties of LiFePO&lt;sub&gt;4&lt;/sub&gt; as Positive Electrode of Li-Ion Batteries for HEV Application

Enhanced Electrochemical Properties of LiFePO<sub>4</sub> as Positive Electrode of Li-Ion Batteries for HEV Application