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The electrical properties of nanostructured Gd-doped CeO₂ (n-GDC) as a function of temperature and water partial-pressure were investigated using ac and dc measurements. For n-GDC, protonic conductivity prevails under wet condition and at low temperatures ( 200℃) under both dry and wet conditions. The grain boundaries in n-GDC were highly selective, being conductive for protonic transport but resistive for oxygen ionic transport. The protonic conductivity reaches about 4 × 10 −7 S/cm at room temperature (RT).

Protonic Conduction Properties of Nanostructured Gd-doped CeO<sub>2</sub> at Low Temperatures