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Experimental electrochemical methods, combined with Monte Carlo simulations, have been employed to investigate the possibility of usi ng 1-decyl-2-(decylthio)-1Hbenzimidazole (T2) as corrosion inhibitor for mild steel in a 1 M HCl medium. This inhibitor was found to be of the mixed type. The re sults derived from EIS indicate that the charge transfer resistance has increased with t he increase in the inhibitor concentration. The inhibitory mechanism was explore d by the potential of zero charge (Epzc) measurement at the solution/metal interface. The inhibitor adsorption has followed Langmuir adsorption isotherm. Surface morp h logy results showed the compound adsorbed film on a mild steel surface. The molecule interactions with the mild steel surface were simulated based on Monte Ca rlo simulation approach using Fe(111) crystal surface as a representative metalli c surface.

portugaliae electrochimica acta

Adsorption and Corrosion Inhibition Effect of 2-Mercaptobenzimidazole (Surfactant) on a Carbon Steel Surface in an Acidic Medium: Experimental and Monte Carlo Simulations