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The carbon conductor is exfoliated from the aluminum current collector when overcharged. That exfoliation results from stress caused by volume expansion of the carbon conductor, not from electrolyte wetting, internal electrostatic force, or a carbon intercalation reaction. Electrolysis of the anion is the reason. Therefore, we are taking care to evaluate adhesion properties not only at coating, but also at charging.

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Adhesion Property between Aluminum Current Collector and Carbon Conductor at Polarized Condition of Positive Electrode for Lithium-Ion Secondary Battery