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Many high-pressure phases of the III-V and II-VI semiconductors have been believed to have the diatomic equivalent of the tetragonal β-tin structure. Recent work has shown this to be incorrect in several cases. It is now shown that the same is strue of all the remaining possibilities AlSb, HgSe, InP and GaP. The phases concerned all have orthorhombic structures of the Cmcm type. The apparent non-existence of the β-tin structure has important implications for the structural systematics.

On the Non-existence of Diatomic .BETA.-Tin as a High-pressure Structure and Structural Systematics of the II-VI,III-V and Group IV Semiconductors.