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A simple and efficient chemoselective oxidation of alcohols to the corresponding aldehydes and ketones using 2,4,6-trimethylpyridinium chlorochromate (TMPCC) in acetonitrile was described. A good range of primary and secondary benzylic alcohols was selectively oxidized under reflux conditions in good to excellent yields.

journal of the chilean chemical society

2,4,6-TRIMETHYLPYRIDINIUM CHLOROCHROMATE (TMPCC) AS AN EFFICIENT AND NOVEL OXIDIZING AGENT FOR THE CHEMOSELECTIVE OXIDATION OF ALCOHOLS TO THE CORRESPONDING CARBONYL COMPOUNDS