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The interactions of the new ligand bis(2-bromophenyl)disulfide (BrPh) 2 S 2 = L with transition metal ions are described. Octahedral complexes [ML 2 Cl 2 (H 2 O) 2 ] (M = Mn(II), Fe(II), Co(II) or Ni(II)) and [CrL 2 Cl 2 (H 2 O) 2 ]Cl were obtained and characterized by physicochemical and spectroscopic methods which suggest that the bis(2-bromophenyl)disulfide behaves as a monodentate ligand

TRANSITION METAL BIS(2-BROMOPHENYL)DISULFIDE COMPLEXES