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Aryl-substituted pyridine(diimine) iron and cobalt dihalide complexes, when activated with excess methylaluminoxane (MAO) in presence of ethylene, exhibit high activity for the production of linear polyethylene. Alteration of the tridentate ligand from pyridine(diimine) to modified a -di imines with pendant phosphine donors (PNN) resulted in efficient iron and cobalt catalysts for ethylene oligomerization. The results are notable as deviation from the pyridine(diimine) scaffold usually results in catalysts with diminished performance. Considerable effort has been devoted to understanding the identity and nature of the propagating species in olefin polymerization, including the spin state of the first row transition metal and the role of the potentially redox-active chelate. Our group has reported the synthesis of cationic bis(imino)pyridine iron and cobalt alkyl complexes that serve as single component catalysts for the polymerization of ethylene (Figure 1). In each case examined, neutral pyridine(diimine) chelates were observed suggesting that redox chemistry with the supporting ligand is not a necessary component for catalytic performance. More recently, we have discovered that addition of the neutral, Lewis acidic borane, B(C6F5)3 to both bis(imino)pyridine and PNN-supported iron butadiene complexes resulted in C-B bond formation to yield the corresponding borate betaine derivatives that are also active for ethylene polymerization and oligomerization, respectively, without the need for an additional activator. Elucidation of the electronic structures of the bis(imino)pyridine derivative established a high spin Fe(II) ion engaged in antiferromagnetic coupling to both chelate (S = 1⁄2) and allyl (S = 1⁄2 ) radical anions.

Cationic Pyridine(diimine) Iron Tethered Alkene Complexes: Synthetic Models For Elusive Intermediates In Iron-Catalyzed Ethylene Polymerization