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Recent advance of bioinspired coordination chemistry of molybdenum and tungsten ions has been reviewed. New synthetic methods to modeling uncommon core structures, sulfido and oxo-sulfido metal centers, involved in molybdenum and tungsten enzyme active sites have been discussed. Reactivity in proton-coupled electron transfer of the model compounds also is included.

Chemistry of Synthetic Models Relevant to the Active Sites of Molybdenum and Tungsten Containing Enzymes