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AgOTf-catalyzed amino-cyclization of 2-(1-alkynyl)-2-alken-1-als or 2-(1-alkynyl)-2-alken-1ones is presented, providing an efficient method for synthesis of 1,2,4-trisubstituted pyrroles or 2,3,5-trisubstituted furans with an arylamino-group function respectively under mild conditions in moderate yields.

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AgOTf-catalyzed cyclization of enynals or enynones with amines: an efficient synthesis of 1,2,4-trisubstituted pyrroles and 2,3,5-trisubstituted furans