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Dimerization of 2-ethynylaniline in the presence of the Ru/Au complexes CpRu(PPh3)Cl(µdppm)AuCl or CpRu(PPh3)I(µ-dppm)AuI results in formation of a quinoline derivative. Monometallic model compounds for the Ru and Au centers did not catalyze the dimerization reaction. This transformation proceeds in higher yield in the absence of solvent.

Dimerization of ethynylaniline to a quinoline derivative using a ruthenium/gold heterobimetallic catalyst