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In investigating the scope and limitations of the sulfur ylide initiated thio-Claisen rearrangement developed in our laboratory, we have been able to efficiently synthesize highly functionalized pyrroloindoline ring systems. This functionality is present in a variety of natural and non-natural products and here we report our synthesis of the debrominated analog of dihydroflustramine C.

Synthesis of the debrominated analog of dihydroflustramine C utilizing a sulfur ylide-initiated thio-Claisen rearrangement