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We have developed a study on the factors that influence the intrasite interactions in the crossmetathesis on solid support. When such interactions are possible, the outcome of the intrasite byproduct depends on the non-immobilized olefin and the precatalyst used. The comparatively poor reactivity of first generation Grubbs precatalyst makes the easier intrasite coupling to succeed.

Solid-phase cross metathesis: the effect of the non-immobilized olefin and the precatalyst on the intrasite interference