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A new benzimidazole-based Pd(II)-complex was prepared and its catalytic activity was evaluated in Heck and Suzuki C-C cross-coupling reactions of aryl and heteroaryl bromides with olefins and arylboronic acids, respectively, under thermal heating using water as a reaction solvent. The factors affecting the optimization of such reactions are studied.

Heck and Suzuki cross-couplings of aryl and heteroaryl bromides in water using a new palladium(II)-complex