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trans-4-Acylamino-2-(polyfluoroalkyl)chromans were synthesized using a Ritter reaction between cis-2-(polyfluoroalkyl)chroman-4-ols and various nitriles.

Stereoselective synthesis of cis-2-(polyfluoroalkyl)chroman-4-ols and trans-4-acylamino-2-(polyfluoroalkyl)chromans