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The crystal structure of the title borane-oxaazacyclophane adduct consists of a tri-dimensional supramolecular array sustained by unconventional N-H···H-B and C-H···H-B dihydrogen bonding and weak C-H···π interactions. The interchain organization in the crystal structure is characterized by weak C-H···H-B dihydrogen bonds.

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Unconventional hydrogen and dihydrogen bonded supramolecular array of a 2,6-dioxa-9,16-diaza-1,3(1,2),4(1,4)-tribenzenacycloheptadecaphane-borane adduct