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A convenient four-step synthesis of progesterone fused to N-arylcarbamoylthiocarbonylpyrazoline at position 16,17 starting from 3β-acetoxypregna-5,16-dien-20-one was developed.

Synthesis of 1'-arylcarbamoylthiocarbonyl-3'-methyl-3-oxo-androst-4-eno[16α,17α-d]pyrazolines