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The Claisen-Schmidt condensation of 1-aryl-2-(N-methylanilino)-1-ethanones with aromatic aldehydes in the presence of sodium hydroxide in aqueous alcohol led to the formation of hitherto unknown (Z)-1,3-diaryl-2-(N-methylanilino)-2-propen-1-ones. The structure and stereochemistry of the products were elucidated from H, C and 2D NMR spectroscopic data and nuclear Overhauser effect.

A facile stereoselective synthesis of (Z)-1,3-diaryl-2-(N-methyl-anilino)-2-propen-1-ones