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The carbanion of 4,4-dimethyl-2-(1-phenylethyl)-4,5-dihydro-1,3-oxazole adds 1 to nitroarenes in the position para to the nitro group: oxidation of the produced σ H adducts with dichlorodicyanobenzoquinone (DDQ) gives para-substituted nitroarenes whereas oxidation with dimethyldioxirane (DMD) leads to para- substituted phenols.

Oxidative nucleophilic substitution of hydrogen in nitroarenes with an oxazoline stabilised carbanion