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Octafluoro[2.2](1,4)anthraceno-paracyclophane slowly undergoes a clean photodimerization upon being exposed, in solution, to fluorescent light. X-ray crystal analysis of this photodimer indicated that the aromaticity of the anthracene ring directly involved in the paracyclophane system was observed to be destroyed by forming a cyclobutane ring, with the two molecules linked to each other in a head to tail fashion.

An unprecedented photodimerization of an anthraceno[2.2]paracyclophane