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We report a simple and straightforward route to hetero-functionalized cyclopropanes by addition of heteroatom nucleophiles to ethyl 2-(diethoxymethyl)cycloprop-2-ene-1-carboxylate. The resulting donor-acceptor substituted cyclopropane are useful synthetic intermediates owing to their high functionalization. Particular emphasis is placed in the stereochemical outcome of this reaction.

Diastereoselective addition of heteroatom nucleophiles to ethyl 2-(diethoxymethyl)-cycloprop-2-ene-1-carboxylate