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The intramolecular additions of C-centered neutral α-aminoalkyl radicals onto suitably positioned C-C double bonds provide a ready access into functionalized carbocycles and heterocycles. This strategy offers considerable versatility in the selection of starting materials since a number of methods using different functional groups and reagents are available for αaminoalkyl radical generation. This review covers the recent progress in this field.

Recent developments in cyclization reactions of α-aminoalkyl radicals