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The reactions of nucleophilic substitution of the chlorine atoms and the nitro group in 1,2dichloroand 1-chloro-2-nitrobenzenes 2 by the thiolate anions generated from 2,2-disubstituted 1,3-propanedithiols 1 under the action of bases afford dihydrobenzodithiepines 3.

Synthesis of dihydrobenzodithiepines by the reactions of 1,2-dichloro- and 1-chloro-2-nitrobenzenes with 1,3-dithiols