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2,3-Dihydro-10b-H-[1,3]oxazolo[3,2-c]-[1,3]benzoxazines have been prepared by the reaction of N-(2-hydroxybenzylidene)-1,2-aminoalkanols with formaldehyde in 43–84% yield. The effect of substituents in the N-(2-hydroxybenzylidene)-1,2-aminoalkanols upon the structures and yields of the condensation products has been shown.

Condensation of N-(2-hydroxybenzylidene)-1,2-aminoalkanols with formaldehyde