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Synthesis of 10,10-dimethyltricyclo[7.2.2.0]tridec-12-ene-3,11-dione 5 via cycloaddition of a cyclohexa-2,4-dienone with cycloheptadiene and its photoreaction to tricyclic compound 3 containing BCD ring system of phorbol is presented.

Synthesis and photochemical reaction of tricyclo[7.2.2.0] tridecanes: a novel entry to the BCD carbon framework of phorbol