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This account is intended to provide a brief survey on our contribution in the field of enantiopure sulfinyl homo and hetero dienes which we are able to obtain via enantiopure sulfenic acids. The chemistry of these sulfinyl-dienes was mainly developed taking into account the practical importance of stereoselective homo and hetero Diels-Alder cycloadditions, able to supply useful intermediates in the synthesis of target molecules.

Synthesis and Diels-Alder reactivity of sulfinyl homo- and heterodienes obtained via enantiopure sulfenic acids