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The regiochemistry of the domino metathesis reaction of 2-endo substituted 7-oxanorbornenic allyl amines and allyl ethers have been studied. The results lead to two alternative reaction pathways, starting either by ring-opening metathesis of the endocyclic C=C bond or by carbometallation of the C=C bond of the alkenyl chain.

Regioselective domino metathesis of 2-substituted 7-oxanorborn-5-enes