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Cyclohexene derivatives 12 and 14 having an oxygen-functional group at C-(4) were found to undergo smooth vinylketene-cyclohexedienone cyclisations to furnish the highly functionalised bicyclic compounds 13, 15 and 16 in good chemical yields.

Preparation of functionalised bicycles by means of vinyl ketene-cyclohexadienone electrocyclis­ations: an entry into terpenoid precursors

Preparation of functionalised bicycles by means of vinyl ketene-cyclohexadienone electrocyclisations: an entry into terpenoid precursors