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Lithio-2,6-dibromo-3,5-difluoropyridine (2), readily prepared from 2,4,6-tribromo-3,5 difluoropyridine 1, reacts with a range of electrophiles to give various functionalised pyridine derivatives. A subsequent X-ray crystallographic study of 2,6-dibromo-3,5-difluoro(4-pyridyl) methylphenyl ketone 3e shows an unusual solid state lattice packing arrangement.

Polyhalogenated heterocyclic compounds.Part 43. Reactions of 4-lithio-2,6-dibromo-3,5 difluoro pyridine