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Single crystals of Cu7GeS5I–Cu7GeSe5I superionic solid solutions were grown by chemical transport. Their electrical conductivity in the frequency range 1.0·10–1.2·10 Hz and in the temperature range 100–300 K was measured; the compositional dependences of the electrical conductivity and activation energy were obtained. Electrochemical studies of Cu7GeS5I– Cu7GeSe5I solid solutions were performed, the character of compositional variation of the electrode potential and the range of the electrochemical stability at S→Se substitution were determined. The optical absorption edge of Cu7GeS5I–Cu7GeSe5I superionic solid solutions in the temperature range 77–300 K were studied; the compositional dependences of the optical pseudogap and Urbach energy were obtained.

lithuanian journal of physics

Electrical conductivity, electrochemical and optical properties of Cu7GeS5I-Cu7GeSe5I superionic solid solutions