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The results of a systematic study of   spiro   -cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and  31 P NMR results in order to investigate the relationship between the δ P   spiro    shift values and endocyclic and exocyclic NPN bond angles, and electron density transfer parameters. Structural parameters derived from 11 types of the ferrocenyl cyclophosphazene derivatives with 5- to 7-membered   spiro   -rings introduced to the literature from our research group were studied and compared with each other.

turkish journal of chemistry

Phosphorus-nitrogen compounds- (Part 50): correlations between structuralparameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)