Improvement of electrochemical and structural properties of polycarbazole by simultaneous electrodeposition of chitosan
Author(s) -
Didem Balun Kayan,
Veysel Polat
Publication year - 2017
Publication title -
turkish journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.239
H-Index - 46
eISSN - 1303-6130
pISSN - 1300-0527
DOI - 10.3906/kim-1604-95
Subject(s) - cyclic voltammetry , chronoamperometry , dielectric spectroscopy , fourier transform infrared spectroscopy , composite number , chitosan , chemistry , scanning electron microscope , electrochemistry , electrolyte , chemical engineering , polymer chemistry , analytical chemistry (journal) , composite material , materials science , electrode , organic chemistry , engineering
Polycarbazole/chitosan composite materials were synthesized electrochemically at various loadings of chitosan (Chi). Their electrochemical, structural, thermal, and morphological characterizations were investigated by cyclic voltammetry, chronoamperometry, electrochemical impedance spectroscopy, Fourier transform infrared spectroscopy, thermal gravimetry, and scanning electron microscopy. Further electrical conductivity was measured using a four-point probe technique. The electrochemical results showed that the electrical conductivity of the polymeric composite film was increased by increasing the amount of Chi in the electrolyte medium. The as-prepared composite films exhibited enhanced electrical conductivity and structural properties of polycarbazole due to the presence of Chi in the composite films.
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