Deposition and characterization of Cu$_{9}$S$_{5}$ nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C$_{6}$H$_{3}$(NO$_{2})_{2}$-3,5]$_{2}$Cu(II) and [(Et)(Bu)NC(S)NC(O)C$_{6}$H$_{4}$-4-NO$_{2}$]$_{2}$Cu(II) complexes by colloidal thermolysis method